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Corresponding Author(s)

黄略略（1983—），女，深圳职业技术大学教授，博士。E-mail：huangll@szpu.edu.cn

Abstract

The article summarizes the various application scenarios of terahertz spectroscopy technology in the food industry,analyzing its effectiveness,advantages,and disadvantages in different applications.In food traceability,this technology combines spectral and image signals to achieve precise predictions through mathematical models,effectively identifying issues such as food adulteration.In component detection,through qualitative and quantitative analyses,terahertz technology enables the detection of pesticide residues,veterinary drug residues,and food additives to ensure food safety.For quality monitoring,the technology can leverage spectral absorption characteristics and integrate them with mathematical models to monitor quality changes,such as oil oxidation and mold growth in agricultural products.

Publication Date

4-3-2025

First Page

197

Last Page

205

DOI

10.13652/j.spjx.1003.5788.2024.80524

References

[1] ZHANG L H,ZHANG M,MUJUMDAR A S.Terahertz spectroscopy:a powerful technique for food drying research [J].Food Reviews International,2023,39(3):1 733-1 750.
[2] 王与烨,李海滨,葛梅兰,等.太赫兹成像技术及其应用 [J].激光与光电子学进展,2023,60(18):46-61.WANG Y Y,LI H B,GE M L,et al.Terahertz imaging technology and its application [J].Laser & Optoelectronics Progress,2023,60(18):46-61.
[3] 李堂玥,牟达,夏鹏宇,等.基于太赫兹时域光谱系统共光路光 纤 耦 合 系 统 的 设 计 及 误 差 分 析 [J].中 国 激 光,2024,51(8):174-183.LI T Y,MU D,XIA P Y,et al.Design and error analysis of a fiber coupling system based on THz-TDS common optical path[J].Chinese Journal of Lasers,2024,51(8):174-183.
[4] ZAMAN A,ALMOND N W,LU Y Z,et al.Graphene-based external optoelectronic terahertz modulators for high speed wireless communications [C]// 14th UK-Europe-China Workshop on Millimetre-Waves and Terahertz Technologies (UCMMT ).Lancaster:IEEE,2021:13-15.
[5] YAN Z Y,ZHU L G,MENG K,et al.THz medical imaging:from in vitro to in vivo [J].Trends in Biotechnology,2022,40(7):816-830.
[6] BAXTER J B,GUGLIETTA G W.Terahertz spectroscopy [J].Analytical Chemistry,2011,83(12):4 342-4 368.
[7] JÖRDENS C,KOCH M.Detection of foreign bodies in chocolate with pulsed terahertz spectroscopy [J].Optical Engineering,2008,47(3):037003.
[8] YE D D,WANG W Z,ZHOU H T,et al.Characterization of thermal barrier coatings microstructural features using terahertz spectroscopy [J].Surface and Coatings Technology,2020,394:125836.
[9] LI Z.Wavelength selection for quantitative analysis in terahertz spectroscopy using a genetic algorithm [J].IEEE Transactions on Terahertz Science and Technology,2016,6(5):658-663.
[10] WAHAIA F,KASALYNAS I,SELIUTA D,et al.Terahertz spectroscopy for the study of paraffin-embedded gastric cancer samples [J].Journal of Molecular Structure,2015,1079:391-395.
[11] LU S H,ZHANG X,ZHANG Z Y,et al.Quantitative measurements of binary amino acids mixtures in yellow foxtail millet by terahertz time domain spectroscopy [J].Food Chemistry,2016,211:494-501.
[12] SCHERGER B,WIETZKE S,SCHELLER M,et al.Characterization of micro-powders for the fabrication of compression molded THz lenses [J].Journal of Infrared,Millimeter,and Terahertz Waves,2011,32(7):943-951.
[13] SCHERGER B,BORN N,JANSEN C,et al.Compression molded terahertz transmission blaze-grating [J].IEEE Transactions on Terahertz Science and Technology,2012,2(5):556-561.
[14] BUSCH S F,BORN N,KOCH M,et al.Terahertz reflection gratings made by room-temperature high-pressure molding [J].Journal of Infrared,Millimeter,and Terahertz Waves,2013,34(7):413-415.
[15] WICHMANN M,MONDOL A S,KOCIC N,et al.Terahertz plastic compound lenses [J].Applied Optics,2013,52(18):4 186-4 191.
[16] KIM S J,BORN B,HAVENITH M,et al.Real-time detection of protein-water dynamics upon protein folding by terahertz absorption spectroscopy [J].Angewandte Chemie International Edition,2008,47(34):6 486-6 489.
[17] DAMIAN V,LOGOFĂTU P C,VASILE T.3D THz hyperspectrum applied in security check-in [C]// Advanced Topics in Optoelectronics,Microelectronics,and Nanotechnologies VIII.Constanta:SPIE,2016:25-28.
[18] REDO-SANCHEZ A,SALVATELLA G,GALCERAN R,et al.Assessment of terahertz spectroscopy to detect antibiotic residues in food and feed matrices [J].Analyst,2011,136(8):1 733-1 738.
[19] JORNET J M,AKYILDIZ I F.Channel modeling and capacity analysis for electromagnetic wireless nanonetworks in the terahertz band [J].IEEE Transactions on Wireless Communications,2011,10(10):3 211-3 221.
[20] MALHOTRA I,RANJAN JHA K,SINGH G.Analysis of highly directive photoconductive dipole antenna at terahertz frequency for sensing and imaging applications [J].Optics Communications,2017,397:129-139.
[21] TU W L,ZHONG S C,INCECIK A,et al.Defect feature extraction of marine protective coatings by terahertz pulsed imaging [J].Ocean Engineering,2018,155:382-391.
[22] HE M X,AZAD A K,YE S H,et al.Far-infrared signature of animal tissues characterized by terahertz time-domain spectroscopy [J].Optics Communications,2006,259(1):389-392.
[23] ZEITLER J A,TADAY P F,NEWNHAM D A,et al.Terahertz pulsed spectroscopy and imaging in the pharmaceutical setting-a review [J].Journal of Pharmacy and Pharmacology,2007,59(2):209-223.
[24] UENO Y,RUNGSAWANG R,TOMITA I,et al.Quantitative measurements of amino acids by terahertz time-domain transmission spectroscopy [J].Analytical Chemistry,2006,78(15):5 424-5 428.
[25] 延凯悦,冯毅,马静艳,等.太赫兹应用分析和展望 [J].邮电设计技术,2020 (4):6-10.YAN K Y,FENG Y,MA J Y,et al.Analysis and prospect of terahertz technology application [J].Designing Techniques of Posts and Telecommunications,2020 (4):6-10.
[26] 孙一健,王继芬.太赫兹时域光谱技术在食品、药品和环境领 域 中 的 应 用 研 究 进 展 [J].激 光 与 光 电 子 学 进 展,2022,59(16):12-21.SUN Y J,WANG J F.Research progress of terahertz time-domain spectroscopy in food,drugs,and environment [J].Laser & Optoelectronics Progress,2022,59(16):12-21.
[27] 吴遵红,徐义,李昌胜,等.太赫兹波在无损检测领域的应用[J].科技创新与应用,2021,11(9):180-182.WU Z H,XU Y,LI C S,et al.Application of terahertz wave in nondestructive testing field [J].Technology Innovation and Application,2021,11(9):180-182.
[28] JOHNSON J B,WALSH K B,NAIKER M,et al.The use of infrared spectroscopy for the quantification of bioactive compounds in food:a review [J].Molecules,2023,28(7):|3 215.
[29] GRASSI S,ALAMPRESE C.Advances in NIR spectroscopy applied to process analytical technology in food industries [J].Current Opinion in Food Science,2018,22:17-21.
[30] 周旭,杨倩倩,张进,等.基于便携式近红外光谱仪的黄桃腐败时间快速预测 [J].食品与机械,2024,40(5):101-106,187.ZHOU X,YANG Q Q,ZHANG J,et al.Rapid prediction of yellow peach spoilage time based on portable near infrared spectrometer [J].Food & Machinery,2024,40(5):101-106, 187.
[31] 邵淑娟,李丽,温磊,等.中红外光谱模型用于烤肉中苯并 [a]芘 的 快 速 检 测 和 评 估 [J].食 品 与 机 械,2023,39(3):34-37,102.SHAO S J,LI L,WEN L,et al.Rapid detection and evaluation of benzo [a]pyrene in barbecue by mid-infrared spectroscopy model [J].Food & Machinery,2023,39(3):34-37,102.
[32] WU L,TANG X M,WU T,et al.A review on current progress of Raman-based techniques in food safety:from normal Raman spectroscopy to SESORS [J].Food Research International,2023,169:112944.
[33] WANG K Q,LI Z L,LI J J,et al.Raman spectroscopic techniques for nondestructive analysis of agri-foods:a state-of-the-art review [J].Trends in Food Science & Technology,2021,118:490-504.
[34] PETERSEN M,YU Z L,LU X N.Application of Raman spectroscopic methods in food safety:a review [J].Biosensors,2021,11(6):187.
[35] 王留留,孙方涛.表面增强拉曼光谱技术在食品安全检测领域中的应用 [J].食品与机械,2024,40(1):212-218.WANG L L,SUN F T.Application of surface-enhanced Raman spectroscopy in food safety detection [J].Food & Machinery,2024,40(1):212-218.
[36] 胡家勇,周陶鸿,姚晓帆,等.表面增强拉曼光谱法筛查保健酒中那非类药物 [J].食品与机械,2022,38(9):64-71.HU J Y,ZHOU T H,YAO X F,et al.Screening of PDE- 5 inhibitors in health wine by surface-enhanced Raman spectroscopy [J].Food & Machinery,2022,38(9):64-71.
[37] RAVIKANTH L,JAYAS D S,WHITE N D G,et al.Extraction of spectral information from hyperspectral data and application of hyperspectral imaging for food and agricultural products [J].Food and Bioprocess Technology,2017,10(1):1-33.
[38] KANG Z L,ZHAO Y C,CHEN L,et al.Advances in machine learning and hyperspectral imaging in the food supply chain[J].Food Engineering Reviews,2022,14(4):596-616.
[39] BAIANO A.Applications of hyperspectral imaging for quality assessment of liquid based and semi-liquid food products:a review [J].Journal of Food Engineering,2017,214:10-15.
[40] 章恺,朱丽芳,李入林,等.基于改进 WOA-LSSVM 和高光谱的 猕 猴 桃 糖 度 无 损 检 测 [J].食 品 与 机 械,2024,40(5):107-112,226.ZHANG K,ZHU L F,LI R L,et al.Non destructive detection of kiwifruit sugar content based on improved WOA-LSSVM and hyperspectral analysis [J].Food & Machinery,2024,40(5):107-112,226.
[41] 赵静远,张俊芹,孙梅,等.基于高光谱成像的羊肉掺假可视化无损定量检测 [J].食品与机械,2022,38(10):61-68.ZHAO J Y,ZHANG J Q,SUN M,et al.Visualization of lamb adulteration based on hyperspectral imaging for non-destructive quantitative detection [J].Food & Machinery,2022,38(10):61-68.
[42] AFSAH-HEJRI L,HAJEB P,ARA P,et al.A comprehensive review on food applications of terahertz spectroscopy and imaging [J].Comprehensive Reviews in Food Science and Food Safety,2019,18(5):1 563-1 621.
[43] FENG C H,OTANI C.Terahertz spectroscopy technology as an innovative technique for food:current state-of-the-Art research advances [J].Critical Reviews in Food Science and Nutrition,2021,61(15):2 523-2 543.
[44] FU Y,REN Y Q,SUN D W.Novel analysis of food processes by terahertz spectral imaging:a review of recent research findings [J].Trends in Food Science & Technology,2024,147:104463.
[45] 余静孝,韦庆益,罗洁,等.结合 SG-LDA-SVC 的太赫兹时域光谱快速无损鉴别陈皮产地的方法研究 [J].现代农业装备,2022,43(4):16-21,28.YU J X,WEI Q Y,LUO J,et al.Rapid nondestructive identification of tangerine peel origin based on terahertz time-domain spectroscopy combined with SG-LDA-SVC [J].Modern Agricultural Equipment,2022,43(4):16-21,28.
[46] 杨少壮,李灿,李辰,等.不同贮存年限陈皮的太赫兹光谱和成像的差异分析 [J].现代食品科技,2019,35(12):258-266.YANG S Z,LI C,LI C,et al.The differences in the dried tangerine peels stored for different years revealed by terahertz spectroscopy and imaging [J].Modern Food Science and Technology,2019,35(12):258-266.
[47] 刘 俊 彬.薄 壳 类 作 物 种 子 质 量 THz 光 谱 和 图 像 检 测 应 用 基础研究 [D].南昌:华东交通大学,2021:33.LIU J B.Basic research on application of terahertz spectrum and image thin shell seed quality detection [D].Nanchang:East China Jiaotong University,2021:33.
[48] 孙晓荣,田密,刘翠玲,等.基于太赫兹成像技术的发芽葵花籽无损检测研究 [J].食品科技,2023,48(2):296-302.SUN X R,TIAN M,LIU C L,et al.Nondestructive testing of germinated sunflower seeds based on THz imaging technology[J].Food Science and Technology,2023,48(2):296-302.
[49] 戚淑叶,张振伟,赵昆,等.太赫兹时域光谱无损检测核桃品质的研究 [J].光谱学与光谱分析,2012,32(12):3 390-3 393.QI S Y,ZHANG Z W,ZHAO K,et al.Evaluation of walnut by terahertz nondestructive technology [J].Spectroscopy and Spectral Analysis,2012,32(12):3 390-3 393.
[50] 殷明.基于宽频太赫兹光谱和化学计量学的食用油脂鉴别及掺假检测研究 [D].徐州:中国矿业大学,2017:77.YIN M.Research on the authentication and adulteration detection of the edible oil by broadband terahertz spectroscopy and chemometrics [D].Xuzhou:China University of Mining and Technology,2017:77.
[51] 廉飞宇,付麦霞,葛宏义,等.太赫兹时域光谱识别 4种食用油真实性的研究 [J].中国油脂,2017,42(7):69-73.LIAN F Y,FU M X,GE H Y,et al.Identification of four kinds of edible oils by terahertz time-domain spectroscopy [J].China Oils and Fats,2017,42(7):69-73.
[52] 杨少壮,李灿,李辰,等.基于太赫兹光谱分析技术的肉类鉴别[J].食品与发酵工业,2021,47(11):227-235.YANG S Z,LI C,LI C,et al.Study of meat identification based on terahertz spectroscopy [J].Food and Fermentation Industries,2021,47(11):227-235.
[53] HUANG L L,LIU M L,LI B,et al.Terahertz spectroscopic identification of roast degree and variety of coffee beans [J].Foods,2024,13(3):389.
[54] 马卿效,李春,李天莹,等.太赫兹光谱技术在农药检测领域的研究进展 [J].激光与光电子学进展,2020,57(13):81-89.MA Q X,LI C,LI T Y,et al.Research progress of terahertz spectroscopy in the field of pesticide detection [J].Laser & Optoelectronics Progress,2020,57(13):81-89.
[55] 李健,焦丽娟,李逸楠.太赫兹时域光谱系统在分析氟氯氰菊 酯 正 己 烷 溶 液 中 的 应 用 [J].纳 米 技 术 与 精 密 工 程,2015,13(2):128-133.LI J,JIAO L J,LI Y N.Application of terahertz time-domain spectroscopy in determination of cyfluthrin in n-hexane [J].Nanotechnology and Precision Engineering,2015,13(2):128-133.
[56] 郝国徽,郭昌盛,杜勇,等.除虫脲和高效氯氟氰菊酯的太赫兹光谱及密度泛函理论研究 (英文 ) [J].光散射学报,2013,25(2):198-208.HAO G H,GUO C S,DU Y,et al.Investigation of diflubenzuron and λ-cyhalothrin by terahertz spectroscopy and density functional theory [J].The Journal of Light Scattering,2013,25(2):198-208.
[57] 曹瑶瑶,李霞,白军朋,等.基于 THz-TDS 技术的培氟沙星和氟罗沙星抗生素定性定量检测研究 [J].光谱学与光谱分析,2022,42(6):1 798-1 803.CAO Y Y,LI X,BAI J P,et al.Study on qualitative and quantitative detection of pefloxacin and fleroxacin veterinary drugs based on THz-TDS technology [J].Spectroscopy and Spectral Analysis,2022,42(6):1 798-1 803.
[58] 白军朋,李斌,张淑娟,等.基于太赫兹时域光谱技术的诺氟沙 星 浓 度 检 测 研 究 [J].光 谱 学 与 光 谱 分 析,2021,41(9):2 710-2 716.BAI J P,LI B,ZHANG S J,et al.Study on norfloxacin concentration detection based on terahertz time domain spectroscopy [J].Spectroscopy and Spectral Analysis,2021,41(9):2 710-2 716.
[59] 王立琦,王睿莹,姚静,等.氢化大豆油中反式脂肪酸的太赫兹光谱分析 [J].中国食品学报,2022,22(12):282-289.WANG L Q,WANG R Y,YAO J,et al.THz spectroscopic analysis of trans-fatty acids in hydrogenated soybean oil [J].Journal of Chinese Institute of Food Science and Technology,2022,22(12):282-289.
[60] 康 旭 升,张 光 新,陈 锡 爱,等.反 式 油 酸 的 太 赫 兹 光 谱 研 究[J].光谱学与光谱分析,2011,31(10):2 629-2 633.KANG X S,ZHANG G X,CHEN X A,et al.Terahertz spectroscopic investigation of elaidic acid [J].Spectroscopy and Spectral Analysis,2011,31(10):2 629-2 633.
[61] 胡军,徐振,李茂鹏,等.基于神经网络算法与太赫兹光谱检测技术的奶粉三聚氰胺含量测定 [J].激光与光电子学进展,2020,57(22):370-377.HU J,XU Z,LI M P,et al.Determination of melamine content in milk powder based on neural network algorithm and terahertz spectrum detection [J].Laser & Optoelectronics Progress,2020,57(22):370-377.
[62] 郭以恒,燕芳,赵渺钰,等.基于太赫兹光谱的三聚氰胺定量分析 [J].光学学报,2023,43(19):297-303.GUO Y H,YAN F,ZHAO M Y,et al.Quantitative analysis of melamine based on terahertz spectroscopy [J].Acta Optica Sinica,2023,43(19):297-303.
[63] 黄略略,李辰,李彬,等.太赫兹波谱用于违法添加工业明胶的检测 [J].食品与生物技术学报,2019,38(11):33-39.HUANG L L,LI C,LI B,et al.Studies on illegal additive industrial gelatin detection by terahertz spectroscopy [J].Journal of Food Science and Biotechnology,2019,38(11):33-39.
[64] HUANG L L,LI C,LI B,et al.Studies on qualitative and quantitative detection of trehalose purity by terahertz spectroscopy [J].Food Science & Nutrition,2020,8(4):1 828-1 836.
[65] 杨雨菲,刘翠玲,吴静珠,等.食用油储存期品质变化的太赫兹光谱无损识别 [J].食品科学,2021,42(12):248-254.YANG Y F,LIU C L,WU J Z,et al.Terahertz spectroscopy for non-destructive identification of quality change of edible oils during storage [J].Food Science,2021,42(12):248-254.
[66] 刘伟,刘长虹,余俊杰,等.基于时域太赫兹光谱技术的橄榄油氧化程度检测研究 [J].南方农机,2021,52(5):5-7,17.LIU W,LIU C H,YU J J,et al.Detection of oxidation degree of olive oil based on time-domain terahertz spectroscopy [J].China Southern Agricultural Machinery,2021,52(5):5-7,17.
[67] 孙晓荣,田密,刘翠玲,等.太赫兹衰减全反射技术对板栗果|仁 霉 变 程 度 判 别 研 究 [J].食 品 安 全 质 量 检 测 学 报,2022,13(14):4 527-4 533.SUN X R,TIAN M,LIU C L,et al.Identification of moldy degree of Chinese chestnut kernel by terahertz attenuated total reflection technique [J].Journal of Food Safety & Quality,2022,13(14):4 527-4 533.
[68] 刘翠玲,胡莹,吴静珠,等.基于太赫兹衰减全反射技术的花生霉变程度判别 [J].农业机械学报,2019,50(4):333-338,355.LIU C L,HU Y,WU J Z,et al.Discrimination of peanut mildew degree based on terahertz attenuated total reflection spectroscopy [J].Transactions of the Chinese Society for Agricultural Machinery,2019,50(4):333-338,355.
[69] 葛宏义,王飞,蒋玉英,等.基于宽度学习的太赫兹光谱图像小麦霉变识别研究 [J].量子电子学报,2023,40(3):360-368.GE H Y,WANG F,JIANG Y Y,et al.Identification of wheat mold using terahertz images based on Broad Learning System[J].Chinese Journal of Quantum Electronics,2023,40(3):360-368.
[70] 杨承霖,刘嘉祺,郭芸成,等.结合太赫兹光谱与机器学习的小麦霉变程度判别 [J].食品科学,2023,44(12):343-350.YANG C L,LIU J Q,GUO Y C,et al.Detection of mildew degree of wheat using terahertz spectroscopy and machine learning [J].Food Science,2023,44(12):343-350.
[71] CHUA H S,OBRADOVIC J,HAIGH A D,et al.Terahertz time-domain spectroscopy of crushed wheat grain [C]// IEEE MTT-S International Microwave Symposium Digest.Long Beach,CA:IEEE,2005:17.
[72] REN Y Q,LEI T,SUN D W.In-situ indirect measurements of real-time moisture contents during microwave vacuum drying of beef and carrot slices using terahertz time-domain spectroscopy [J].Food Chemistry,2023,418:135943.
[73] CASTRO-CAMUS E,PALOMAR M,COVARRUBIAS A A.Leaf water dynamics of Arabidopsis thaliana monitored in-vivo using terahertz time-domain spectroscopy [J].Scientific Reports,2013,3:2 910.
[74] GENTE R,BORN N,VOB N,et al.Determination of leaf water content from terahertz time-domain spectroscopic data[J].Journal of Infrared,Millimeter,and Terahertz Waves,2013,34(3):316-323.
[75] HUANG L L,LIAN M M,DUAN X,et al.Studies on the quality and moisture distribution of kiwifruit dried by freeze drying combined with microwave vacuum drying [J].Journal of Food Process Engineering,2021,44(1):e13581.
[76] 陈通,谷航,陈明杰,等.基于气相离子迁移谱对葵花籽油精炼程度的检测 [J].食品科学,2019,40(18):312-316.CHEN T,GU H,CHEN M J,et al.Measurement of the refining degree of sunflower oil based on gas chromatography-ion mobility spectrometry [J].Food Science,2019,40(18):312-316.
[77] 龙锦林,武斌,王春丽,等.液相色谱在食用油中甘油三酯分析检测中的应用 [J].食品工业,2019,40(9):316-319.LONG J L,WU B,WANG C L,et al.Application of liquid chromatography in the analysis of triglycerides in edible oils[J].The Food Industry,2019,40(9):316-319.
[78] 苗雨田,杨悠悠,王浩,等.气相色谱—质谱法测定食用油中3-氯丙醇酯 [J].中国粮油学报,2016,31(11):135-139.MIAO Y T,YANG Y Y,WANG H,et al.Determination of 3-chloropropanol- 1,2-diol (3-MCPD ) esters in edible oil by gas chromatography and mass spectrometry [J].Journal of the Chinese Cereals and Oils Association,2016,31(11):135-139.
[79] JIANG H,ZHANG M,MUJUMDAR A S,et al.Comparison of drying characteristic and uniformity of banana cubes dried by pulse-spouted microwave vacuum drying,freeze drying and microwave freeze drying [J].Journal of the Science of Food and Agriculture,2014,94(9):1 827-1 834.
[80] STANLEY H E,BULDYREV S V,CANPOLAT M,et al.The puzzle of liquid water:a very complex fluid [J].Physica D:Nonlinear Phenomena,1999,133(1/2/3/4):453-462.
[81] YADA H,NAGAI M,TANAKA K.Origin of the fast relaxation component of water and heavy water revealed by terahertz time-domain attenuated total reflection spectroscopy[J].Chemical Physics Letters,2008,464(4/5/6):166-170.
[82] SANTAVICCA D F,REULET B,KARASIK B S,et al.Energy resolution of terahertz single-photon-sensitive bolometric detectors [J].Applied Physics Letters,2010,96(8):083505.

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