Abstract
[Objective] To understand the residue status of six pesticides in fruits and vegetables in northeast Chongqing and the associated health risks to local residents.[Methods] Six pesticides were detected and evaluated for safety using gas chromatography combined with the index of food safety (IFS).[Results] Among the six pesticides,dieldrin was not detected,while the remaining five pesticides were detected.The average residual concentrations of the five pesticides in seven types of fruits and vegetables were as follows:procymidon 0.265 mg/kg,biphenthrin 0.037 mg/kg,beta -cyfluthrin 0.073 mg/kg,cypermethrin 0.060 mg/kg,and deltamethrin 0.025 mg/kg.Among all the samples,beta -cyfluthrin had the highest detection rate (25.34%),followed by procymidon (18.46%),with deltamethrin having the lowest detection rate (5.52%).The exceedance rate was highest for beta -cyfluthrin (1.00%),followed by procymidon (0.90%),while deltamethrin had the lowest exceedance rate (0.09%).The safety evaluation showed that both the single -pesticide average IFS and multiple -pesticide average IFS for the five detected pesticides were all less than 1.[Conclusion] The fruit and vegetable samples sold in northeast Chongqing do not pose significant health risks to humans.
Publication Date
4-3-2025
First Page
72
Last Page
84
DOI
10.13652/j.spjx.1003.5788.2023.81260
Recommended Citation
Qiujie, WU; Yuting, ZHANG; Xin, HE; Wanyi, HUANG; and Zhaodan, WANG
(2025)
"Analysis and safety evaluation of six pesticide residues in fruits and vegetables in northeast Chongqing,"
Food and Machinery: Vol. 41:
Iss.
2, Article 9.
DOI: 10.13652/j.spjx.1003.5788.2023.81260
Available at:
https://www.ifoodmm.cn/journal/vol41/iss2/9
References
[1] 王琳,王耀,胡骁飞,等.免疫分析技术在金刚烷胺残留检测中的应用 [J].食品与机械,2023,39(4):205-210.WANG L,WANG Y,HU X F,et al.Application of immunoassay in the detection of amantadine residues [J].Food & Machinery,2023,39(4):205-210.
[2] 宋宁慧,单正军,郭敏.气相色谱—质谱法检测茶饮料中拟除虫菊酯类农药残留 [J].分析试验室,2011,30(10):102-106.SONG N H,SAN Z J,GUO M.Determination of multi-residues of pyrethroid pesticides in tea drink by GC-MS [J].Chinese |Journal of Analysis Laboratory,2011,30(10):102-106.
[3] SHAO Y L,WANG M,CAO J,et al.A method for the rapid determination of pesticides coupling thin-layer chromatography and enzyme inhibition principles [J].Food Chemistry,2023,416:135822.
[4] 刘 正 才.SPE-MEKC 测 定 蔬 菜 中 农 药 残 留 量 和 杀 扑 磷、氟 苯尼考的电化学分析 [D].南京:南京农业大学,2004:30-40.LIU Z C.Determination of pesticide residues in vegetables by SPE-MEKC and the study on electrochemical methods of methidathion and florfenicol [D].Nanjing:Nanjing Agricultural University,2004:30-40.
[5] 刘超,梅丽宝,尹海飞,等.固相萃取—气相色谱 /质谱法同时测 定 咖 啡 干 果 皮 中 24种 农 药 残 留 [J].食 品 与 机 械,2023,39(1):47-54.LIU C,MEI L B,YIN H F,et al.Simultaneous determination of 24 kinds of pesticide residues in coffee peel by solid phase extraction-gas chromatography-mass spectrometry [J].Food & Machinery,2023,39(1):47-54.
[6] 王思威,王潇楠,常虹,等.氯氟醚菌唑在香蕉和芒果果实中的残留分布 [J].农药学学报,2024,26(1):203-210.WANG S W,WANG X N,CHANG H,et al.Residue distribution of mefentrifluconazole in banana and mango fruits[J].Chinese Journal of Pesticide Science,2024,26(1):203-210.
[7] 常利民,张洋,汪春明,等.鸡蛋、鸡肉及奶粉中 22种有机氯农药残留的测定 [J].食品与生物技术学报,2022,41(5):98-105.CHANG L M,ZHANG Y,WANG C M,et al.Determination of 22 organochlorine pesticides in egg,chicken and milk powder[J].Journal of Food Science and Biotechnology,2022,41(5):98-105.
[8] 胡付照,陈正行,李鹤,等.茶叶中农药残留标准及检测方法研究进展 [J].食品与生物技术学报,2018,37(10):1 009-1 014.HU F Z,CHEN Z X,LI H,et al.Research advance of pesticide residues standards and new detection methods in tea [J].Journal of Food Science and Biotechnology,2018,37(10):1 009-1 014.
[9] 丁葵英,许文娟,郭礼强,等.液相色谱—串联质谱法测定葱属蔬菜中的噻虫嗪、多菌灵等 5种农药的残留量 [J].食品与生物技术学报,2016,35(4):424-428.DING K Y,XU W J,GUO L Q,et al.Determination of 5 pesticide residues in allium vegetables by liquid chromatography-tandem mass spectrometry [J].Journal of Food Science and Biotechnology,2016,35(4):424-428.
[10] HOU X,HAN M,DAI X H,et al.A multi-residue method for the determination of 124 pesticides in rice by modified QuEChERS extraction and gas chromatography-tandem mass spectrometry [J].Food Chemistry,2013,138(2/3):1 198-1 205.
[11] ANDRADE G C R M,FREGUGLIA R M O,FURLANI R P Z,et al.Determination of pesticide residues in tomato using dispersive solid-phase extraction and gas chromatography/ion trap mass spectrometry [J].Journal of the Brazilian Chemical Society,2011,22(9):1 701-1 708.
[12] 熊大伟,吴恩凯,李桂晓.液液萃取—气相色谱质谱法测定环 境 水 体 中 有 机 磷 农 药 [J].环 境 与 发 展,2020,32(5):113,115.XIONG D W,WU E K,LI G X.Determination of organophosphorus pesticides in environmental water by liquid-liquid extraction-gas chromatography-mass spectrometry [J].Environment and Development,2020,32(5):113,115.
[13] 张权,周贻兵,林野,等.基质分散固相萃取结合气相色谱串联质谱法快速筛查皂角米中的 73种农药残留 [J].现代食品科技,2021,37(11):354-363.ZHANG Q,ZHOU Y B,LIN Y,et al.Rapid screening of 73 pesticide residues in gleditsia sinensis seeds by matrix solid-phase dispersion extraction combined with gas chromatography-mass spectrometry [J].Modern Food Science and Technology,2021,37(11):354-363.
[14] 刘莹,王盼雪,孙妍,等.利用磁固相萃取技术结合表面增强拉 曼 散 射 快 速 检 测 葡 萄 汁 中 的 三 唑 磷 [J].食 品 安 全 质 量 检测学报,2022,13(23):7 554-7 562.LIU Y,WANG P X,SUN Y,et al.Rapid determination of triazophos in grape juice by magnetic solid phase extraction combined with surface enhanced Raman scattering [J].Journal of Food Safety & Quality,2022,13(23):7 554-7 562.
[15] 黄小波,刘维平.基于 QuEChERS 的UHPLC-MS/MS 同时检测 鸡 蛋 中 19种 农 药 残 留 量 [J].食 品 与 机 械,2021,37(10):56-60.HUANG X B,LIU W P.Simultaneous determination of 19 kinds of pesticide residues in eggs by UHPLC-MS/MS based on QuEChERS [J].Food & Machinery,2021,37(10):56-60.
[16] 赵杰斌,邓浩,徐振林.基于食品安全指数法的台山市蔬菜和 水 果 农 药 残 留 风 险 评 估 [J].现 代 食 品 科 技,2023,39(6):277-283.ZHAO J B,DENG H,XU Z L.Risk assessment of pesticide residues in vegetables and fruits from Taishan City based on the index of food safety [J].Modern Food Science and Technology,2023,39(6):277-283.
[17] 柴勇,杨俊英,李燕,等.基于食品安全指数法评估重庆市蔬菜中农药残留的风险 [J].西南农业学报,2010,23(1):98-102.CAI Y,YANG J Y,LI Y,et al.Risk estimate of vegetables based on food safety indexes methods in Chongqing [J].Southwest China Journal of Agricultural Sciences,2010,23(1):98-102.
[18] 左晓磊,刘培,齐琨,等.2018 年石家庄市蔬菜中农药残留及慢 性 膳 食 暴 露 评 估 [J].食 品 安 全 质 量 检 测 学 报,2020,11 (18):6 562-6 567.ZUO X L,LIU P,QI K,et al.Assessment of pesticide residues and chronic dietary exposure in vegetables in Shijiazhuang city in 2018 [J].Journal of Food Safety & Quality,2020,11(18):6 562-6 567.
[19] GE Q,MEI J,CHEN S,et al.Deposition,dissipation,and minimum effective dosage of the fungicide carbendazim in the pepper-field ecosystem [J].Pest Management Science,2020,76(3):907-916.
[20] 胡 家 萌.3种 农 药 在 叶 菜 类 蔬 菜 中 的 残 留 与 消 解 规 律 研 究[D].南京:南京农业大学,2019:1-7.HU J M.Study on residues and digestion of three kinds of pesticides in leafy vegetables [D].Nanjing:Nanjing Agricultural University,2019:1-7.
[21] 刘芳,朱国华,韩育梅.乌兰察布市自产蔬菜农药残留检测与 膳 食 暴 露 风 险 评 估 [J].江 西 农 业 学 报,2022,34(7):182-189.LIU F,ZHU G H,HAN Y M.Detection and dietary risk assessment of pesticide residues in self-produced vegetables in Ulanqab City [J].Acta Agriculturae Jiangxi,2022,34(7):182-189.
[22] 荆建忠,刘俊丽.2016 —2018 年滨州市市售蔬菜农药残留调查[J].预防医学论坛,2019,25(4):306-308,311.JING J Z,LIU J L.Survey on pesticide residues in vegetables,Binzhou city,2016 —2018 [J].Preventive Medicine Tribune,2019,25(4):306-308,311.
[23] 秦培余,隋佳琪.蔬菜、水果中农药残留浅析 [J].食品安全导刊,2019 (36):28.QIN P Y,SUI J Q.Analysis of pesticide residues in vegetables and fruits [J].China Food Safety Magazine,2019 (36):28.
[24] 刘顺字,廖远东,郭淑贞,等.叶菜上三大类农药残留现状及原因探析 [J].园艺与种苗,2021,41(4):57-59.LIU S Y,LIAO Y D,GUO S Z,et al.Present situation and reasons of pesticide residues in three major types of leafy vegetables [J].Horticulture & Seed,2021,41(4):57-59.
[25] ZHAO Y T,YUE Z C,ZHONG X M,et al.Distribution of primary and secondary metabolites among the leaf layers of headed cabbage (Brassica oleracea var.capitata ) [J].Food Chemistry,2020,312:126028.
[26] ZHAO E C,XIE A Q,WANG D,et al.Residue behavior and risk assessment of pyraclostrobin and tebuconazole in peppers under different growing conditions [J].Environmental Science and Pollution Research International,2022,29(56):84 096-84 105.
[27] 张忠祥,沈琦,康佳乐,等.不同种植方式西瓜果实农药残留的比较 [J].食品工业科技,2022,43(15):265-271.ZHANG Z X,SHEN Q,KANG J L,et al.Comparison of pesticide residues in watermelon fruits with different planting methods [J].Science and Technology of Food Industry,2022,43(15):265-271.
[28] KOMAGATA O,KASAI S,TOMITA T.Overexpression of cytochrome P 450 genes in pyrethroid-resistant Culex quinquefasciatus [J].Insect Biochemistry and Molecular Biology,2010,40(2):146-152.
[29] CHANG J,HAO W Y,XU Y Y,et al.Stereoselective degradation and thyroid endocrine disruption of lambda-cyhalothrin in lizards (Eremias argus ) following oral exposure[J].Environmental Pollution,2018,232:300-309.
[30] 陈仁,陈群航,杜宜新,等.福州地区灰霉病菌对腐霉利和嘧霉胺抗药性测定 [J].福建农业学报,2015,30(2):180-183.CHEN R,CHEN Q H,DU Y X,et al.Resistance detection of botrytis cinerea in Fuzhou to procymidone and pyrimethanil[J].Fujian Journal of Agricultural Sciences,2015,30(2):180-183.
[31] 樊晓青,陆贻通,汪传炳.腐霉利在生菜和土壤中的残留动态研究[J].上海交通大学学报 (农业科学版 ),2007,25(6):570-573.FAN X Q,LU Y T,WANG C B.Residue dynamics of procymidone in lettuce and soil [J].Journal of Shanghai Jiao Tong University (Agricultural Science ),2007,25(6):570-573.
[32] 杨庆喜,纪明山,谷祖敏.氰霜唑及其主要代谢物 CCIM 在番茄 和 葡 萄 上 的 残 留 行 为 及 膳 食 暴 露 风 险 评 估 [J].农 药 学 学 报,2020,22(5):815-822.YANG Q X,JI M S,GU Z M.Residues behavior and dietary exposure risk assessment of cyazofamid and its main metabolite CCIM in tomato and grape [J].Chinese Journal of Pesticide Science,2020,22(5):815-822.