Abstract
The sample was purifid by solid phase extraction column. A simple, fast, accurate method for determination of Imibenconazole in fruits and vegetables was developed by ultra high performance liquid chromatography-tandem quadrupole mass spectrometry (UPLC—MS—MS). The linear range of the method is from 1.0 μg/L to 100 μg/L ,and the correlation coefficients were 0.998 7~0.999 6, and the detection limit is 1.0 μg/kg. The proposed method has high sensitivity and good reproducibility for determining Imibenconazole.
Publication Date
2-28-2015
First Page
75
Last Page
77
DOI
10.13652/j.issn.1003-5788.2015.01.017
Recommended Citation
Jingchun, CHEN; Sheng, CHEN; Yabin, HE; and Xiaoping, ZHENG
(2015)
"Determination of imibenconazole in fruits and vegetables by ultra high performance liquid chromatography-tandem quadrupole mass spectrometry,"
Food and Machinery: Vol. 31:
Iss.
1, Article 17.
DOI: 10.13652/j.issn.1003-5788.2015.01.017
Available at:
https://www.ifoodmm.cn/journal/vol31/iss1/17
References
[1] 毕强, 余鲸年.Imibenconazole——一种新的杀菌剂[J].农药译丛,1996, 18(4): 63~64.
[2] 李薇, 赵文芳, 冷欣夫.梨果及土壤中亚胺唑及其代谢物的气相色谱分析[J]. 色谱, 1998, 16(6): 508~509.
[3] 熊芳,戴华,黄志强.气相色谱法测定葡萄中烯唑醇农药的残留量[J]. 色谱, 2002, 20(4): 383~384.
[4] 周芳梅, 蔡双福, 文灿, 等. 亚胺唑在土壤生态系统中的检测方法及持久性研究[J]. 农业环境科学学报, 2008,27(1):234~237.
[5] 黄士忠, 王继军, 黄永春, 等.酰胺唑及其代谢物在柑橘和土壤中的残留动态研究[J]. 农业环境科学学报, 2004, 23(1): 181~185.
[6] Akiko Kaihara, Kimihiko Yoshii, Yukari Tsumura, et al. Multiresidue analysis of pesticides in fresh fruits and vegetables by supercritical fluid Extraction and HPLC[J]. Journal of Health Science, 2000,46(5):336~342.
[7] 熊芳,戴华,李拥军,等. 高效液相色谱法测定葡萄中烯唑醇农药残留量[J]. 农药, 2002, 43(8):22~23.
[8] 全国农药残留实验研究协作组编. 农药残留量实用检测方法手册 (第二卷)[S]. 北京:化学工业出版社,2001:428~437
[9] 王岩松,张春晖,张春野,等. 高效液相色谱—串联质谱法测定 蔬菜和水果中氟吗啉的残留量[J]. 分析化学研究报告, 2012, 40(2):286~291.
[10] 刘长令.世界农药大全 杀菌剂卷[M].北京: 化学工业出版,2006: 80~82.
[11] 农业部农药检定所,山西省农药重点实验室.NY/T 788—2004 农药残留试验准则[S]. 北京: 中国农业出版社,2004.