Abstract
To further improve the performance of non-enzymatic electrochemical glucose sensor, a one-step in-situ oxidation method was used to prepare nickel oxide material directly grown on nickel foam. Moreover, the indium and tin ions were doped into the nickel oxide material during the growth process, and an In-Sn@NiO composite could be obtained. XPS measurement indicated that the indium and tin ions were successfully doped into nickel oxide material. Through the SEM images, the surface of the doped nickel oxide electrode showed a structure of nanorods instead of nanosheets. Compared with undoped material, the structures could benefit the transport of surface particles. From the results of electrochemical sensitivity test towards glucose, this electrode exhibited a remarkable performance with a sensitivity of 91.9 mA/(μmol·L-1·cm2) and the limit of detection was 0.02 μmol/L.
Publication Date
1-28-2018
First Page
57
Last Page
61
DOI
10.13652/j.issn.1003-5788.2018.01.011
Recommended Citation
Jiadan, LI; Hongmei, XU; and Xu, ZHAO
(2018)
"A high sensitivity non-enzymatic electrochemical glucose sensor based on In-Sn@NiO composite,"
Food and Machinery: Vol. 34:
Iss.
1, Article 11.
DOI: 10.13652/j.issn.1003-5788.2018.01.011
Available at:
https://www.ifoodmm.cn/journal/vol34/iss1/11
References
[1] 崔英磊, 钱锋, 张彰. 一种基于无酶葡萄糖传感器的修饰电极及电化学性能[J]. 上海大学学报, 2016, 22(9): 1-7.
[2] 李文进, 刘霞, 李蓉卓, 等. 电化学传感器在农药残留检测中的研究进展[J]. 食品与机械, 2013, 29(4): 241-245.
[3] 庄贞静, 肖丹, 李毅. 无酶葡萄糖电化学传感器的研究进展[J]. 化学研究与应用, 2009, 21(11): 1 486-1 493.
[4] DERIKVANDI H, NEZAMZADEH-EJHIEH A. Synergistic effect of p-n heterojunction, supporting and zeolite nanoparticles in enhanced photocatalytic activity of NiO and SnO2[J]. Journal of Colloid and Interface Science, 2017, 490(1): 314-327.
[5] 罗梅兰, 叶云, 梁超香, 等. 生物检测技术在食品检验中的应用[J]. 食品与机械, 2006, 22(2): 96-104.
[6] 于浩, 陈小霞, 冯晓, 等. 氧化铜-过氧化聚吡咯-还原氧化石墨烯复合膜修饰电极非酶检测葡萄糖[J]. 分析测试学，2017, 36(8): 969-974.
[7] HELLER A, FELDMAN B. Electrochemical glucose sensors and their applications in diabetes management[J]. Chemical Revi-ews, 2008, 108(7): 2 482-2 505.
[8] 姚伟. 葡萄糖传感电极的制备与性能研究[D]. 济南: 山东师范大学, 2015: 26-29.
[9] 牟莹. 电化学非酶葡萄糖传感器的研究[D]. 杭州: 浙江师范大学, 2012: 19-31.
[10] 辛华, 陈丽波, 史鸿雁, 等. 电化学沉积制备纳米结构铜电极及其葡萄糖检测性能[J]. 高等学校化学学报, 2014, 35(3): 482-487.
[11] WANG Chueh-han, YANG Cheng-hsien, CHANG Jeng-kuei. High-selectivity electrochemical non-enzymatic sensors based on graphene/Pd nanocomposites functionalized with designated ionic liquids[J]. Biosensors &Bioelectronics, 2017, 89(1): 483-488.
[12] GALANT A L, KAUFMAN R C, WILSON J D. Glucose: Detection and analysis[J]. Food Chemistry, 2015, 188(1): 149-160.
[13] 唐明宇. 国内无酶葡萄糖电化学传感器研究进展[J]. 广东化工, 2013, 40(1): 79-80.
[14] ZHAO Yue, FAN Luo-zhen, HONG Bo, et al. Nonenzymatic detection of glucose using three-dimensional Pt Ni nanoclusters electrodeposited on the multiwalled carbon nanotubes[J]. Sensors and Actuators B: Chemical, 2016, 231(1): 800-810.
[15] 刘忠银, 史天录, 张雪, 等. 利用纳米材料制备葡萄糖传感器的研究进展[J]. 功能材料与器件学报, 2015, 21(4): 24-30.
[16] LIU Min-min, LIU Ru, CHEN Wei. Graphene wrapped Cu2O nanocubes: Non-enzymatic electrochemical sensors for the detection of glucose and hydrogen peroxide with enhanced stability[J]. Biosensors & Bioelectronics, 2013, 45(1): 206-212.
[17] 张衷译, 王力南, 赵兵, 等. 基于Ni(OH)2/NiOOH媒介电化学氧化葡萄糖的循环伏安法分析[J]. 北京化工大学学报: 自然科学版, 2017, 44(3): 1-7.
[18] 申宗旭. 镍基纳米材料在电化学葡萄糖传感器的研究与应用[D]. 北京: 北京交通大学, 2016: 3-20.
[19] KIMMEL D W, LEBLANC G, MESCHIEVITZ M E, et al. Electrochemical sensors and biosensors[J]. Analytical Chemistry, 2012, 84: 685-707.
[20] WANG Guang-feng, HE Xiu-ping, WANG Ling-ling, et al. Non-enzymatic electrochemical sensing of glucose[J]. Microchimica Acta, 2013, 180: 161-186.