•  
  •  
 

Abstract

Oil samples were extracted with methanol, and BHA, BHT and TBHQ in food were detected by gas chromatography. Result: When the concentration of BHA, BHT and TBHQ was in the range of 0.01~0.20 mg/mL, all of the correlation coefficients of BHA, BHT and TBHQ had good linear relation with r>0.999, with the detection limits<0.5 μg/mL. The recovery rate of the method met the requirements of laboratory determination, and the standard deviation was between 1.07~3.10 and the relative standard deviation was less than 5%.

Publication Date

11-28-2018

First Page

79

Last Page

81

DOI

10.13652/j.issn.1003-5788.2018.11.017

References

[1] 王朝杰, 李倩, 杨天明. 气相色谱法测定食品中叔丁基对苯二酚定量方法的探讨[J]. 浙江农业科学, 2017, 58(11): 2 026-2 028, 2 033.
[2] 王澍, 周玮婧, 江小明. 气相色谱法检测食品中的抗氧化剂BHA, BHT和TBHQ及不确定度评定[J]. 粮食与油脂, 2017, 30(10): 90-92.
[3] 邹哲祥, 李耀平, 林艳, 等. 气相色谱法测定食品包装材料中五种抗氧化剂迁移量[J]. 分析试验室, 2017, 36(9): 1 067-1 070.
[4] 李东旭. 凝胶渗透色谱-气相色谱法测定食品中BHA、BHT[J].食品研究与开发, 2016, 37(15): 186-189.
[5] 张勋, 刘韬, 吴连鹏, 等. 高效液相色谱-串联质谱法测定多种食品中7种酚类抗氧化剂和对羟基苯甲酸酯类防腐剂[J]. 食品与发酵工业, 2016, 42(11): 206-211.
[6] 国家质量监督检验检疫总局. GB/T 23373-2009 食品中抗氧化剂丁基羟基茴香醚(BHA)、二丁基对甲酚(BHT)与特丁基对苯二酚(TBHQ)的测定[S]. 北京: 中国标准出版社, 2009: 12-13.
[7] TRINDADE G, APARECIDO M, CARAMI T, et al. A new voltammetric method for the simultaneous determination of the antioxidants TBHQ and BHA in biodiesel using multi-walled carbon nanotube screen-printed electrodes[J]. Fuel, 2013, 105(1): 306-313.
[8] 林春晓, 付斌, 叶泽群, 等. 气相色谱法测定食用油脂中BHA, BHT样品前处理方法研究[J]. 中国热带医学, 2005, 5(4): 812-814.
[9] 国家质量监督检验检疫总局. GB/T 5009.30-2003 食品中叔丁基羟基茴香醚(BHA)与2, 6二叔丁基 对甲酚(BHT)的测定[S]. 北京: 中国标准出版社, 2003: 5.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.