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Abstract

In order to reveal the change of cellulose structure and physical property caused by ultra micronization, cellulose power was treated through different concentrations of sodium hydroxide and then broken by using high pressure jet. The microstructure, size and physical properties of microfabrication were explored. After pretreatment with 10% NaOH solution (70 ℃, 1 h) and high pressure jet treatment, the diameter of the crude microfabrication decreases from 5.0~50.0 μm to 0.1~1.0 μm, and the length decreases from 20.0~200.0 μm to 1.0~10.0 μm. The peak value of cellulose particle size distribution curve was reduced from 158.0 μm to 10.0 μm. The specific surface area was improved by 3.0~ 5.5 times. The results indicated that the swelling of cellulose microfiber bundles after alkali pretreatment could reduce the mechanical properties of the cellulose, and its particle size decreased significantly by the spraying of high pressure jet. XRD results showed that there was no obvious change in the crystallinity and thermal stability after high pressure jet. However, the crystallinity of cellulose decreased 10% after alkalization. Alkali pretreatment improved the micronization degree of cellulose by high pressure jet.

Publication Date

1-28-2020

First Page

36

Last Page

41

DOI

10.13652/j.issn.1003-5788.2020.01.005

References

[1] 蓝海军,刘成梅,涂宗财,等.大豆膳食纤维的湿法超微粉碎与干法超微粉碎比较研究[J].食品科学,2007,28(6):171-174.
[2] 朱建华,杨晓泉.超声处理对大豆分离蛋白流变学性质的影响[J].食品科学,2005,26(12):52-57.
[3] 胡宝松,张绍英.超高压射流破碎对大豆分离蛋白功能性质的影响[J].大豆通报,2007,89(4):30-34.
[4] GOMEZ H C,SERPA A,VELASQUEZ-COCK J.Vegetable nanocellulose in food science:A review[J].Food Hydrocolloids,2016,57:178-186.
[5] EYHOLZER C,BORDEANU N,LOPEZ-SUEVOS F,et al.Preparation and characterization of water-redispersible nanofibrillated cellulose in powder form[J].Cellulose,2010,17:19-30.
[6] 蔡杰,吕昂,周金平,等.纤维素科学与材料[M].北京:化学工业出版社,2015:277-279.
[7] FERRER A,PAL L,HUBBE M.Nanocellulose in packaging:Advances in barrier layer technologies[J].Industrial Crops and Products,2017,95:574-582.
[8] AZEREDO H M C,ROSA M F,MATTOSOB L H C.Nanocellulose in bio-based food packaging applications[J].Industrial Crops and Products,2017,97:664-671.
[9] YANG Quan-ling,FUKUZUMI H,SAITO T,et al.Transparent cellulose films with high gas barrier properties fabricated from aqueous alkali/urea solutions[J].Biomacromolecules,2011,12:2 766-2 771.
[10] KHAN A,WEN Yang-bing,HUQ T,et al.Cellulosic nanomaterials in food and nutraceutical applications:A review[J].Journal of Agricultural and Food Chemistry,2018,66:8-19.
[11] MOON ROBERT J,MARTINI A,NAIRN J.Cellulose nanomaterials review:structure,properties and nanocomposites[J].Chemical Society Reviews,2011,40:3 941-3 994.
[12] ABE K,YANO H.Formation of hydrogels from cellulose nanofibers[J].Carbohydrate Polymers,2011,85:733-737.
[13] ABE K,YANO H.Cellulose nanofiber-based hydrogels with high mechanical strength[J].Cellulose,2012,19:1 907-1 912.
[14] NECHYPORCHUK O,BELGACEUR M N,BRAS J.Production of cellulose nanofibrils:A review of recent advances[J].Industrial Crops and Products,2016,93:2-25.
[15] SIQUEIRA G,TAPIN-LINGUA S,BRAS J,et al.Morphological investigation of nanoparticles obtained from combined mechanical shearing,and enzymatic and acid hydrolysis of sisal fibers[J].Cellulose,2010,17:1 147-1 158.
[16] DINAND E,VIGON M,CHANZY H,et al.Mercerization of primary wall cellulose and its implication for the conversion of cellulose I→cellulose II[J].Cellulose,2002,9(1):7-18.
[17] CHEN Wen-shuai,YU Hai-peng,LIU Yi-xing,et al.Individualization of cellulose nanofibers from wood using high-intensity ultrasonication combined with chemical pretreatments[J].Carbohydrate Polymers,2011,83:1 804-1 811.
[18] 潘利华,徐学玲,罗建平.超声辅助提取水不溶性大豆膳食纤维及其物理特性[J].农业工程学报,2011,27(9):387-392.
[19] ZHANG Xue-xia,YU Yan,LI Wan-ju,et al.An efficient dispersive agent:KCl for ultrasonic preparation of microfibrillated cellulose(MFC)[J].Bio Resources,2015,10:6 635-6 642.
[20] QUIEVY N,JACQUET N,SCLAVONS M,et al.Influence of homogenization and drying on the thermal stability of microfibrillated cellulose[J].Polymer Degradation and Stability,2010,95:306-314.
[21] PAAKKO M,ANKERFORS M,KOSONEN H,et al.Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels[J].Biomacromolecules,2007,8:1 934-1 941.
[22] SIRO I,PLACKETT D,HEDENQVIST M,et al.Highly transparent films from carboxymethylated microfibrillated cellulose:The effect of multiple homogenization steps on key properties[J].Journal of Applied Polymer Science,2011,119:2 652-2 660.
[23] JAFARI S M,HE Ying-he,BHANDARI B.Production of sub-micron emulsions by ultrasound and microfluidization techniques[J].Journal of Food Engineering,2007,82:478-488.
[24] 张俊华,宋海农,林鹿,等.高压均质化处理对微纤化纤维素性质的影响[J].纤维素科学与技术,2009,17(3):7-11.
[25] AMIRALIAN N,ANNAMALAI P K,MEMMOTT P,et al.Isolation of cellulose nanofibrils from Triodia pungens via different mechanical methods[J].Cellulose,2015,22:2 483-2 498.

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