Development of rapid detection technique for potassium content in cigarette paper

Authors

CHEN Peng-fei, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Cytochemistry, Changsha University of Science and Technology, Changsha, Hunan 410114 , China
WANG Si-lu, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Cytochemistry, Changsha University of Science and Technology, Changsha, Hunan 410114 , China
YU Sai-bo, Technology Center, Hunan China Tobacco Industry Co., Ltd., Changsha, Hunan 410007 , China
PENG Xing, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Cytochemistry, Changsha University of Science and Technology, Changsha, Hunan 410114 , China
HUANG Jia-ying, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Cytochemistry, Changsha University of Science and Technology, Changsha, Hunan 410114 , China
XIAO Yang, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Cytochemistry, Changsha University of Science and Technology, Changsha, Hunan 410114 , China
XIAO Zhong-liang, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Cytochemistry, Changsha University of Science and Technology, Changsha, Hunan 410114 , China
CAO Zhong, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, Hunan 410114 , China ；Hunan Provincial Key Laboratory of Cytochemistry, Changsha University of Science and Technology, Changsha, Hunan 410114 , China

Abstract

Objective:A method for simple and rapid determination of potassium content in cigarette paper will be built for workshops of cigarette factory.Methods:An ion-selective electrode method was used by comparing with the pretreatment methods for cigarette paper samples and potential response behaviors of potassium ion-selective electrodes in different buffer solutions.Results: The potassium ion selective electrode possessed excellent response performance for K+in lithium acetate buffer solution (0.1 mol/L, pH 7.0) with a linear response range of 1.0×10-5~1.0×10-2mol/L, a slope of 55.79 mV/dec(25 ℃), and a lower limit of detection of 2.14×10-6mol/L. The average relative standard deviations of the K+selective electrode on cigarette paper samples were 0.55% for intra-day test and 2.8% for inter-day test, both less than 5%. The test results of the electrode method were in well agreement with that of ion chromatography, with an average relative deviation of 4.1% (n=10) and recoveries between 95.0% and 101.9%. It was demonstrated effectively through a consecutive test over one week.Conclusion: Among the pretreatment methods for cigarette paper samples, the ultrasonic extraction of potassium ions with 1% diluted acetic acid for 30 min has been found to be fast, simple and environmentally friendly. The ion-selective electrode method is accurate and reliable, which is suitable for the rapid detection of potassium in cigarette paper.

Publication Date

9-2-2022

First Page

96

Last Page

102

DOI

10.13652/j.spjx.1003.5788.2022.60008

Recommended Citation

Peng-fei, CHEN; Si-lu, WANG; Sai-bo, YU; Xing, PENG; Jia-ying, HUANG; Yang, XIAO; Zhong-liang, XIAO; and Zhong, CAO (2022) "Development of rapid detection technique for potassium content in cigarette paper," Food and Machinery: Vol. 38: Iss. 6, Article 18.
DOI: 10.13652/j.spjx.1003.5788.2022.60008
Available at: https://www.ifoodmm.cn/journal/vol38/iss6/18

References

[1] 尹升福,谭蓉,银董红,等.金属盐对卷烟纸裂解致孔及主流烟气中CO释放量的影响[J].烟草科技,2016,49（8）:35-43.YIN Sheng-fu,TAN Rong,YIN Dong-hong,et al.Pyrolysis of cigarette paper:effects of metal salts on pore formation and carbon monoxide release in mainstream smoke[J].Tobacco Science & Technology,2016,49（8）:35-43.
[2] 杨金龙,朱萍,程利侠,等.钾盐对卷烟烟气影响的研究进展[J].湖南文理学院学报（自然科学版）,2018,30（4）:64-67.YANG Jin-long,ZHU Ping,CHENG Li-xia,et al.Recent advances in influence of potassium salts on cigarette smoke[J].Journal of Hunan University of Arts and Science（Natural Science Edition）,2018,30（4）:64-67.
[3] 段瑞海,李红娟,冯俊杰,等.2种有机酸钾盐卷烟纸助剂对卷烟热解性能的影响[J].西南农业学报,2021,34（7）:1 395-1 399.DUAN Rui-hai,LI Hong-juan,FENG Jun-jie,et al.Effect oftwo kinds of organic acid potassium salt cigarette paper additives on pyrolysis performance of cigarette[J].Southwest China Journal of Agricultural Sciences,2021,34（7）:1 395-1 399.
[4] 杨韧强,毛多斌,黄朝章,等.卷烟纸中不同助燃剂类型对卷烟感官品质的影响[J].轻工学报,2018,33（2）:50-54.YANG Ren-qiang,MAO Duo-bin,HUANG Chao-zhang,et al.Effects of different types of combustion supporting agent in cigarette paper on cigarette sensory quality[J].Journal of Light Industry,2018,33（2）:50-54.
[5] 李欢,王建民,王豪礼,等.卷烟纸参数对卷烟持灰能力的影响[J].食品与机械,2021,37（6）:207-212.LI Huan,WANG Jian-min,WANG Hao-li,et al.Influence of cigarette paper parameters on cigarette ash holding capacity[J].Food & Machinery,2021,37（6）:207-212.
[6] 田志章,李海霞,张春涛,等.卷烟纸及烟丝钾钠比差异对卷烟主流烟气影响[J].食品工业,2019,40（9）:170-173.TIAN Zhi-zhang,LI Hai-xia,ZHANG Chun-tao,et al.Differenteffects of potassium-sodium ratio variation of cigarette paper and cut-tobacco on mainstream smoke[J].The Food Industry,2019,40（9）:170-173.
[7] 李劲峰,向能军,李春,等.卷烟纸助燃剂含量对卷烟烟气有害物质的影响[J].中国造纸,2012,31（6）:32-35.LI Jin-feng,XIANG Neng-jun,LI Chun,et al.Theinfluence of combustion-supporting additives in cigarette paper on the harmful chemicals in mainstream smoke of the cigarette[J].China Pulp & Paper,2012,31（6）:32-35.
[8] ZHAO D,DAI Y,CHEN K,et al.Effect of potassium inorganic and organic salts on the pyrolysis kinetics of cigarette paper[J].Journal of Analytical and Applied Pyrolysis,2013,102:114-123.
[9] 马胜楠,王建民,常冰冰,等.烟丝和卷烟纸中金属元素对自由燃烧速率的影响[J].食品与机械,2019,35（9）:64-68.MA Sheng-nan,WANG Jian-min,CHANG Bing-bing,et al.Effects of metal elements on free burning speed in cutrag and cigarette paper[J].Food & Machinery,2019,35（9）:64-68.
[10] SHEN J,LI J,QIAN X,et al.A review on engineering of cellulosic cigarette paper to reduce carbon monoxide delivery of cigarettes[J].Carbohydrate Polymers,2014,101:769-775.
[11] 刘源,银董红,尹升福,等.卷烟纸裂解致孔对主流烟气中HCN释放量的影响[J].烟草科技,2016,49（12）:46-53.LIU Yuan,YIN Dong-hong,YIN Sheng-fu,et al.Effect of combustion improver on combustion behavior of cigarette paper by simultaneous TG/DSC detection[J].Tobacco Science & Technology,2016,49（12）:46-53.
[12] LI H,YI L,LI D,et al.Effect of combustion improver on combustion behavior of cigarette paper by simultaneous TG/DSC detection[J].Chinese Journal of Chemistry,2010,28（8）:1 322-1 326.
[13] 郭英.离子色谱法测定水样中的钠、钾、镁、钙离子[J].环境科学导刊,2016,35（S1）:190-191.GUO Ying.Test of sodium and potassium and magnesium and calcium in water by ion chromatography[J].Environmental Science Survey,2016,35（S1）:190-191.
[14] 许永,李超,杨乾栩,等.连续流动法测定烟草中总糖、还原糖、氯、钾含量的不确定度评定[J].食品与机械,2017,33（12）:61-64,75.XU Yong,LI Chao,YANG Qian-xiang,et al.Uncertainty evaluation of the determination of total sugar,reducing sugar,chlorine,potassium in tobacco[J].Food & Machinery,2017,33（12）:61-64,75.
[15] 冯广林,李力,朱立军,等.微波消解样品—离子色谱法测定卷烟纸中钠、钾、镁、钙的含量[J].理化检验:化学分册,2012,48（4）:449-451,455.FENG Guang-lin,LI Li,ZHU Li-jun,et al.IC determination of sodium,potassium,magnesium and calcium in cigarette paper with microwave assisted sample digestion[J].Physical Testing and Chemical Analysis Part B:Chemical Analysis,2012,48（4）:449-451,455.
[16] 杨皓,王小平,严春芳,等.原子吸收光谱法与离子色谱法测定卷烟纸中钾钠离子的比较研究[J].中国测试,2017,43（S1）:42-47.YANG Hao,WANG Xiao-ping,YAN Chun-fang,et al.Comparative study on determination of potassium and sodium in cigarette paper by ASS and IC[J].China Measurement & Test,2017,43（S1）:42-47.
[17] 俞汝勤.离子选择性电极分析法[M].北京:人民教育出版社,1980:6-17.YU Ru-qin.Ion-selective electrode analysis[M].Beijing:People's Education Press,1980:6-17.
[18] 韩冰,徐厚平,崔波.小麦粉中溴酸钾检测方法的比较[J].食品与机械,2012,28（4）:104-105,142.HAN Bing,XU Hou-ping,CUI Bo.Comparison of detection methods on potassium bromate in wheat flour[J].Food & Machinery,2012,28（4）:104-105,142.
[19] 林辉概,柳爱平,肖丹,等.长链烷基锍脲衍生物用作阴离子选择电极膜载体[J].高等学校化学学报,1994,15（3）:352-355.LIN Hui-gai,LIU Ai-ping,XIAO Dan,et al.Long-chain alkylthiouronium derivatives as carriers for anion-selective electrode[J].Chemical Journal of Chinese Universities,1994,15（3）:352-355.
[20] 曹忠,林辉概,王彬锋,等.以不对称长链叔胺为中性载体的PVC膜pH电极的研究[J].分析测试学报,1995,14（4）:1-5.CAO Zhong,LIN Hui-gai,WANG Bin-feng,et al.Long-chain unsymmetrical tertiary amines as neutral carrier in PVC membrane pH electrode[J].Journal of Instrumental Analysis,1995,14（4）:1-5.
[21] CAO Z,GONG F C,LI H P,et al.Approach on quantitative structure-activity relationship for design of a pH neutral carrier containing tertiary amino group[J].Analytica Chimica Acta,2007,581（1）:19-26.
[22] MOSTAFA I M,MENG C D,DONG Z X,et al.Potentiometric sensors for the determination of pharmaceutical drugs[J].Analytical Sciences,2022,38:23-37.
[23] PARRILLA M,CUARTERO M,CRESPO G A,et al.Wearable potentiometric ion sensors[J].TrAC Trends in Analytical Chemistry,2019,110:303-320.
[24] MIRAS M,GARCÍA M,MARTÍNEZ V,et al.Inexpensive ion-selective electrodes for the simultaneous monitoring of potassium and nitrate concentrations in nutrient solutions[J].Analytical Methods,2021,13（31）:3 511-3 520.
[25] PIETRZAK K,WARDAK C.Comparative study of nitrate all solid state ion-selective electrode based on multiwalled carbon nanotubes-ionic liquid nanocomposite[J].Sensors and Actuators B:Chemical,2021,348:130720.
[26] 钟平胜,田春妹,任佳丽.电化学修饰电极在食品重金属快速检测中的研究进展[J].食品与机械,2018,34（4）:192-196.ZHONG Ping-sheng,TIAN Chun-mei,REN Jia-li.Advances in application of electrochemical modified electrode in the fast detection of heavy metal[J].Food & Machinery,2018,34（4）:192-196.
[27] LI X Q,LIANG H Q,CAO Z,et al.Simple and rapid mercury ion selective electrode based on 1-undecanethiol assembled Au substrate and its recognition mechanism[J].Materials Science and Engineering C:Materials for Biological Applications,2017,72:26-33.
[28] 曹忠,李文锋,彭与煜,等.基于低功耗蓝牙传输的电位型嵌入式无线传感监测系统的研制[J].分析化学,2019,47（2）:229-236.CAO Zhong,LI Wen-feng,PENG Yu-yu,et al.Design and fabrication of embedded wireless monitoring system based on bluetooth low energy transmission for potentiometric sensors[J].Chinese Journal of Analytical Chemistry,2019,47（2）:229-236.
[29] YI H C,GE L,LISAK G.Highly reproducible solid contact ion selective electrodes:Emerging opportunities for potentiometry:A review[J].Analytica Chimica Acta,2021（282）:338304.
[30] JIANG T,YIN B,LIU X,et al.Porous carbon-based robust,durable,and flexible electrochemical device for K+ detection in sweat[J].Analyst,2022,147（6）:1 144-1 151.
[31] ZHANG Z,PAPAUTSKY I.Miniature ion-selective electrodes with mesoporous carbon black as solid contact[J].Electroanalysis,2021,33（10）:2 143-2 151.
[32] 全国烟草标准化技术委员会.卷烟纸中钾、钠、钙、镁的测定火焰原子吸收光谱法:YC/T 274—2008[S].北京:中国标准出版社,2008:1-5.National Technical Committee for Tobacco Standardization.Determination of potassium,sodium,calcium,magnesium in cigarette paper with flame atomic absorption spectrometry:YC/T 274—2008[S].Beijing:Standards Press of China,2008:1-5.