Abstract
［Objective］ To analyze the effects of migration temperature,heating time,and copper content on the migration of copper from regreen Indocalamus leaves to food simulants.［Methods］ Regreen Indocalamus leaves were prepared by being soaked in copper sulfate pentahydrate solutions.Food simulants included ultrapure water,2.5% (mass fraction ) sodium chloride solution,4% (volume fraction ) acetic acid solution,10% (mass fraction ) white sugar solution,soybean oil,and 5‰ (mass fraction ) sodium bicarbonate solution.The effects of migration temperature,heating time,and copper content on the migration amount of copper from regreen Indocalamus leaves were analyzed.［Results］］ Except for soybean oil,the migration amount of copper from regreen Indocalamus leaves was the largest in 4% acetic acid solution,followed by 2.5% sodium chloride solution.When the migration temperature was 100 ℃,the copper migration amount in all food simulants reached peaks in 2 hours,and then decreased as time elapsed;when the migration time was 24 hours,the migration amount reached peaks in ultrapure water,2.5% sodium chloride solution and soybean oil at 40 ℃,and the migration amount reached peaks in 4% acetic acid solution and 10% white sugar solution at 25 ℃;The higher the copper content of regreen Indocalamus leaves is,the greater the migration amount is.［Conclusion］ The properties of food simulants,heating time,and temperature are important factors affecting the copper migration from regreen Indocalamus leaves.As the copper content of regreen Indocalamus leaves is higher,the migration amount is greater,and acidic food is more conducive to copper migration.
Publication Date
4-25-2025
First Page
33
Last Page
38
DOI
10.13652/j.spjx.1003.5788.2024.80652
Recommended Citation
Liping, LIU; Zhijun, ZHANG; Honggui, SHEN; Hongquan, LUO; and Haiqun, CHEN
(2025)
"Effect of migration conditions on copper migration from regreen Indocalamus leaves,"
Food and Machinery: Vol. 41:
Iss.
3, Article 5.
DOI: 10.13652/j.spjx.1003.5788.2024.80652
Available at:
https://www.ifoodmm.cn/journal/vol41/iss3/5
References
[1] 石艳,章发盛.硫酸铜浸泡箬叶包裹粽子实验中铜离子迁移分析 [J].食品安全导刊,2017 (19):68-70.SHI Y,ZHANG F S.Analysis of copper ion migration in Indocalamus leaves with cupric sulfate soaked [J].China Food Safety Magazine,2017 (19):68-70.
[2] 陈召桂,朱玲琳,张路.微波消解—原子吸收法测定不同条件下返青箬叶中铜离子的迁移情况 [J].食品安全质量检测学报,2019,10(9):2 791-2 794.CHEN Z G,ZHU L L,ZHANG L.Determination of copper ion migration in regreen indocalamus leaves under different conditions by microwave digestion and atomic absorption spectrometry [J].Journal of Food Safety & Quality,2019,10(9):2 791-2 794.
[3] 蒋珊珊.真空包装肉粽中铜和油脂氧化的风险评估 [D].厦门:集美大学,2019:8-9.JIANG S S.Risk assessment of copper and oil oxidation in vacuum-packed meat rice dumplings [D].Xiamen:Jimei University,2019:8-9.
[4] VIJ M,SANKARANARAYANAN S,SANKARANARAYANAN V S,et al.Giant cell hepatitis in copper toxicosis [J].Journal of Clinical and Experimental Hepatology,2022,12(2):719-720.
[5] YU H T,WANG D,ZOU L Y,et al.Proteomic alterations of brain subcellular organelles caused by low-dose copper exposure:implication for Alzheimer's disease [J].Archives of Toxicology,2018,92(4):1 363-1 382.
[6] GAETKE L M,CHOW-JOHNSON H S,CHOW C K.Copper:toxicological relevance and mechanisms [J].Archives of Toxicology,2014,88(11):1 929-1 938.
[7] 洪凰,周黎霞,邵铭,等.粽子国家标准中关键指标的研究 [J].食品工程,2015 (2):34-37,51.HONG H,ZHOU L X,SHAO M,et al.Research on critical indicators in rice dumplings national standard [J].Food Engineering,2015 (2):34-37,51.
[8] 杜青.电感耦合等离子体发射光谱法测定粽叶和粽子中的铜[J].现代科学仪器,2017 (2):101-103.DU Q.Determination of copper in reed leaves and zongzi by inductively coupled plasma optical emission spectrometry [J].Modern Scientific Instruments,2017 (2):101-103.
[9] 葛芳芳,朱洪亮,钱非.微波消解 -ICP-MS 法测定粽叶中 11种元素 [J].食品工业,2023,44(8):293-295.GE F F,ZHU H L,QIAN F.Determination of 11 elements in reed leaves by microwave digestion with ICP-MS [J].The Food Industry,2023,44(8):293-295.
[10] 刘立萍,陈慧,罗宏泉,等.怀化市食品包装用箬叶所属物种调查和 7种元素含量测定 [J].包装工程,2022,43(5):122-129.LIU L P,CHEN H,LUO H Q,et al.Species survey and seven elements determination of Indocalamus leaves for food packaging in Huaihua [J].Packaging Engineering,2022,43(5):122-129.
[11] SHEN M,CHEN L Y,HAN W,et al.Methods for the determination of heavy metals in indocalamus leaves after different preservation treatment using inductively-coupled plasma mass spectrometry [J].Microchemical Journal,2018,139:295-300.
[12] 高维亚,张茜琳.食品接触用玻璃制品重金属迁移检测分析[J].食品安全导刊,2023 (24):119-122.GAO W Y,ZHANG X L.Detection and analysis of heavy metal migration in glass products for food contact [J].China Food Safety Magazine,2023 (24):119-122.
[13] 禄春强,温士强,罗婵.食品接触用纸中铅、砷迁移分析 [J].中国无机分析化学,2023,13(4):326-329.LU C Q,WEN S Q,LUO C.Analysis on the migration of Pb and As in food contact paper [J].Chinese Journal of Inorganic Analytical Chemistry,2023,13(4):326-329.
[14] 朱晨,蒋鑫.陶瓷包装容器中铅、镉、铜、锌向食醋迁移的研究[J].现代食品,2020,26(18):208-211.ZHU C,JIANG X.Migration of lead,cadmium,copper and zinc from ceramic food packaging materials into vinegar [J].Modern Food,2020,26(18):208-211.
[15] 钟文健,李冕锐,吴婉君,等.食品接触用不锈钢制品在不同浓度含氯模拟物中重金属迁移行为研究 [J].广东化工,2019,46(13):34-35.ZHONG W J,LI M R,WU W J,et al.Migration behavior of heavy metals in stainless steel with different concentrations of chlorine [J].Guangdong Chemical Industry,2019,46(13):34-35.
[16] REBENIAK M,WOJCIECHOWSKA-MAZUREK M,MANIA M,et al.Exposure to lead and cadmium released from ceramics and glassware intended to come into contact with food [J].Roczniki Panstwowego Zakladu Higieny,2014,65(4):301-309.
[17] 刘立萍,沈宏桂,罗宏泉,等.返青箬叶中铜和锌在不同食品模拟物中迁移情况 [J].包装工程,2021,42(21):72-78.LIU L P,SHEN H G,LUO H Q,et al.Migration of copper and zinc of regreen Indocalamus leaves in different food simulants[J].Packaging Engineering,2021,42(21):72-78.
[18] 罗宏泉,刘立萍,沈宏桂,等.返青箬叶中铜向不同食品迁移的模拟研究 [J].包装工程,2023,44(23):135-141.LUO H Q,LIU L P,SHEN H G,et al.Simulation on the migration of copper from regreened Indocalamus leaves to different food [J].Packaging Engineering,2023,44(23):135-141.
[19] 姜紫薇,胡长鹰,石玉杰,等.纳米铜 /聚丙烯复合膜中铜向食品模拟物的迁移及其对膜性能的影响 [J].食品与发酵工业,2019,45(5):68-74.JIANG Z W,HU C Y,SHI Y J,et al.Migration of copper from nano-copper/polypropylene composite films and its effects on the properties of films [J].Food and Fermentation Industries,2019,45(5):68-74.
[20] 任彩霞,汤庆峰,马黎春,等.卤水盐度对铜活化—迁移影响的模拟实验 [J].矿床地质,2012,31(S1):515-516.REN C X,TANG Q F,MA L C,et al.Simulation experiment on the effect of brine salinity on copper activation-migration[J].Mineral Deposits,2012,31(S1):515-516.
[21] 任彩霞,马黎春,汤庆峰,等.低温常压条件下 NaCl-H2O体系对铜活化迁移的影响因素 Ⅱ:pH值和盐度 [J].矿床地质,2015,34(3):581-588.REN C X,MA L C,TANG Q F,et al.Influence factors Ⅱ:pH and salinity on copper activation migration in NaCl-H2O system under condition of atmospheric pressure and low temperature [J].Mineral Deposits,2015,34(3):581-588.
[22] 董玉杰,卢莉璟,徐莉,等.食品接触用不锈钢材料中铬元素迁移规律 [J].食品与发酵工业,2022,48(13):254-260,276.DONG Y J,LU L J,XU L,et al.Migration regularity of Cr from food-contact stainless steel [J].Food and Fermentat ion Industries,2022,48(13):254-260,276.
[23] 卢莉璟,董玉杰,徐莉,等.食品接触用不锈钢材料中镍、铅元素的迁移规律 [J].食品与发酵工业,2022,48(5):150-156.LU L J,DONG Y J,XU L,et al.Migration law of nickel and lead from food-contact stainless steel to food [J].Food and Fermentation Industries,2022,48(5):150-156.
[24] 肖黎,董占华,孙长江,等.陶瓷食品接触材料中铅向酸性食品模拟物迁移的规律 [J].食品科学,2021,42(1):15-24.XIAO L,DONG Z H,SUN C J,et al.Migration pattern of lead from ceramic food contact materials into acidic food simulants [J].Food Science,2021,42(1):15-24.
[25] DONG Z H,LU L X,LIU Z G,et al.Migration of toxic metals from ceramic food packaging materials into acid food simulants [J].Mathematical Problems in Engineering,2014,2 014(1):759018.
[26] DONG Z H,LU L X,LIU Z G.Migration model of toxic metals from ceramic food contact materials into acid food [J].Packaging Technology and Science,2015,28(6):545-556.
[27] LI Y.Migration of metals from ceramic food contact materials.1:effects of pH,temperature,food simulant,contact duration and repeated-use [J].Food Packaging and Shelf Life,2020,24:100493.
[28] ADEREMI T A,ADENUGA A A,OYEKUNLE J A O,et al.High level leaching of heavy metals from colorful ceramic foodwares:a potential risk to human [J].Environmental Science and Pollution Research International,2017,24(20):17 116-17 126.
[29] DEMONT M,BOUTAKHRIT K,FEKETE V,et al.Migration of 18 trace elements from ceramic food contact material:Influence of pigment,pH,nature of acid and temperature [J].Food and Chemical Toxicology,2012,50(3/4):734-743.
[30] 董占华.陶瓷食品包装材料中重金属有害物的迁移试验与理论研究 [D].无锡:江南大学,2015:3-4.DONG Z H.Experimental and theoretical study on migration of heavy metals from ceramic food packaging material [D].Wuxi:Jiangnan University,2015:3-4.