•  
  •  
 

Abstract

The mechanism of free radical chain reaction in lipid oxidation has been summarized. In addition, the role of endogenous trace constituents, such as oxygen, water, free fatty acids, monoacylglycerol and diacylglycerol, etc, on the oil oxidation has been highlighted. The existence of association colloids self-assembled by the surface active minor constituents in vegetable oil and the corresponding action on oil oxidation has all been discussed. The limiting the presence of pro-oxidants and the degrading of antioxidants should be limited strictly during oil refining, for the critical control point to enhance vegetable oil quality.

Publication Date

6-28-2015

First Page

242

Last Page

245,255

DOI

10.13652/j.issn.1003-5788.2015.03.054

References

[1] 陈杭君,毛金林,陈文煊. 富含油脂食品的抗氧化研究现状[J].浙江农业科学,2006, 12(3): 335~337.
[2] 韩山山,孟宗,李进伟. 磷脂与游离脂肪酸对油脂烟点和氧化稳定性的影响[J].中国油脂, 2014,39(4): 23~25.
[3] 曹文明,薛斌,袁超,等. 油脂氧化酸败研究进展[J].粮食与油脂, 2013,26(3):1~5.
[4] 徐芳,卢立新.油脂氧化机理及含油脂食品抗氧化包装研究进展[J].包装工程, 2008, 16(5): 23~26.
[5] 孙丽芹,董新伟,刘玉鹏,等. 脂类的自动氧化机理[J].中国油脂,1998,23(5): 56~57.
[6] Fereidoon Shahidi. Lipid oxidation and improving the oxidative stability[J].Chemical Society Reviews, 2010, 39(3):4 067~4 079.
[7] 谢守华. 油脂的自动氧化和氧化稳定性及检测方法[J].四川粮油科技,1998(4):53~55.
[8] 唐平,金建昌,刘东红. 食品品质的光影响机理及影响因素研究进展[J].粮油加工与食品机械,2005(2): 79~81.
[9] 翁新楚. 脂类的空气氧化[J].中国粮油学报,1993(3): 22~28.
[10] 周胜强. 油脂氧化酸败的主要诱因——光氧化[J]. 四川粮油科技,2003(2):28~29.
[11] 肇立春. 浅谈食用油脂的氧化及其测定[J].粮食与食品工业,2003(1):17~18.
[12] 郑诗超,张锐利,汪学荣. 天然抗氧化剂在油脂中的应用研究[J].食品与机械, 2003(5): 7~8.
[13] 罗晓民,朱靖,付经国. 关于氧化亚硫酸化技术开发皮革加脂剂的探讨[J].皮革化工,1999(6): 4~6.
[14] 李炎,包惠燕,赖旭新. 油脂氧化与抗氧化研究[J].中国食品添加剂,1997(4):15~19.
[15] 徐晓玲. 油脂食品及含油食品包装技术探讨[J].广东包装,2004(3): 26~27.
[16] 向贤伟. 油脂食品的塑料包装研究[J].中国包装,2004(2): 79~81.
[17] 蔡奕文,赵谋明. 天然抗氧化剂发展近况[J].中国油脂,1999(4): 23~26.
[18] 陈新民. 油脂的氧化作用及天然抗氧化剂[J].四川粮油科技,2001(4): 8~10.
[19] Yoshida H. Influence of fatty acids of different unsaturation in the oxidation of purified vegetable oils during microwave irradiation[J]. Journal of Food Agriculture and Environment,1993, 62(6): 41~47.
[20] 张明成.油脂氧化机理及抗氧化措施的介绍[J].粮油加工,2011(3):49~51.
[21] Aubourg S P. Effect of partially hydrolysed lipids on inhibition of oxidation of marine lipids[J]. European Food Research and Technology,2001, 212(5): 540~545.
[22] Paradiso. Effects of free fatty acids on the oxidative processes in purified olive oil[J].Food Research International, 2010, 43(8): 1 389~1 394.
[23] Nielsena C P. Impact of primary amine group from aminophospholipids and amino acids on marine phospholipids stability: Non-enzymatic browning and lipid oxidation[J]. Food Chemistry, 2013,141(6): 879~888.
[24] Mistery B S. Isolation of Sn-a-monolinolein from soybean oil and Its effect on oil oxidative stability[J]. Journal of Food Science, 1987, 52(7):786~790.
[25] Colakoglu. Oxidation kinetics of soybean oil in the presence of monoolein, stearic acid and iron[J]. Food Chemistry, 2007, 101(5): 724~728.
[26] Wang T, Hicks K, Moreau R. Antioxidant activity of phytosterols, oryzanol, and other phytosterol conjugates [J]. Journal of the American Oil Chemists Society, 2002, 79(8):1 201~1 206.
[27] Gomes T. Oligopolymer, diglyceride and oxidized triglyceride contents as measures of olive oil quality[J]. Journal of the American Oil Chemists Society, 1992, 69(7): 1 219~1 223.
[28] Takenaka A, Hosokawa M, Miyashita K. Unsaturated phosphatidylethanolamine as effective synergist in combination with a-tocopherol[J]. Journal of Oleo Science, 2007, 56(12): 511~516.
[29] Bandarra N, Campos R, Batista I, et al. Antioxidant synergy of α-tocopherol and phospholipids[J]. Journal of the American Oil Chemists Society, 1999, 76(4):905~913.
[30] Yoshida H. Participation of free fatty acids in the oxidation of purified soybean oil during microwave heating[J]. Journal of the American Oil Chemists Society, 1992, 69(6): 1 136~1 140.
[31] Chen Bing-can. A critical review of their roles on lipid oxidation chemistry in bulk oils and emulsions[J]. Food Science and Nutrition, 2011, 51(10): 901~916.
[32] Burton G W. Antioxidant action of carotenoids[J].Journal of Nutrition, 1989, 119(6): 109~111.
[33] Malecka M. The effect of squalene on the heat stability of rapeseed oil and model lipids[J]. Food, 1991, 35(6): 541~542.
[34] Mateos R, Domiguez M M, Espartero J L, et al. Antioxidant effect of phenolic compounds, a-tocopherol, and other minor components in virgin olive oil[J]. Journal of Agricultural and Food Chenistry, 2003, 51(8): 7 170~7 175.
[35] Gordon M H. The effect of sterols on the oxidation of edible oils[J]. Food Chemistry, 1983(10): 141~147.
[36] Yoon S H, Jung M Y, Min D B. Effects of thermally oxidized triglycerides on the oxidative stability of soybean oil[J]. Journal of the American Oil Chemists Society, 1988, 65(6): 1 652~1 656.
[37] Gomes T, Caponio F, Paradiao V M. Effects of monoacylglycerols on the oxidative stability of olive oil[J]. Journal of the Science of Food and Agriculture, 2010, 90(8): 2 228~2 232.
[38] Koga T, Terao J. Antioxidant activity of a novel phosphatidyl derivative of vitamin E in lard and its model system[J]. Journal of Agricultural and Food Chemistry, 1994, 42(5): 1 291~1 294.
[39] Chaiyasit W, Elias R J, Mcclements D J. Role of physical structures in bulk oils on lipid oxidation[J]. Food Science and Nutrition,2007, 47(4): 299~317.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.