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Authors

CHEN Danjin, School of Food Science and Technology, Dalian Polytechnic University, Dalian, Liaoning 116034, China; National Engineering Research Center of Milk for Maternal-Infant Health, Beijing 100163, China; Beijing Engineering Research Center of Dairy, Beijing 100
MU Guangqing, School of Food Science and Technology, Dalian Polytechnic University, Dalian, Liaoning 116034, China
JIANG Tiemin, National Engineering Research Center of Milk for Maternal-Infant Health, Beijing 100163, China; Beijing Engineering Research Center of Dairy, Beijing 100163, China; Beijing Sanyuan Foods Co. Ltd., Beijing 100163, China
LIU Jichao, National Engineering Research Center of Milk for Maternal-Infant Health, Beijing 100163, China; Beijing Engineering Research Center of Dairy, Beijing 100163, China; Beijing Sanyuan Foods Co. Ltd., Beijing 100163, China
ZHAO Junying, National Engineering Research Center of Milk for Maternal-Infant Health, Beijing 100163, China; Beijing Engineering Research Center of Dairy, Beijing 100163, China; Beijing Sanyuan Foods Co. Ltd., Beijing 100163, China
LI Hedan, School of Food Science and Technology, Dalian Polytechnic University, Dalian, Liaoning 116034, China; National Engineering Research Center of Milk for Maternal-Infant Health, Beijing 100163, China; Beijing Engineering Research Center of Dairy, Beijing 100
CHEN Lijun, School of Food Science and Technology, Dalian Polytechnic University, Dalian, Liaoning 116034, China; National Engineering Research Center of Milk for Maternal-Infant Health, Beijing 100163, China; Beijing Engineering Research Center of Dairy, Beijing 100

Abstract

The number of kinds and the corresponding capacities of mineral elements in milk and dairy products are key criteria to evaluate their nutritional quality. Thus choosing an efficient, sensitive and rapid detection method for mineral elements is important to the research, production, and trade of dairy products. This paper first discussed the pretreatment method for digesting milk or diary products, and then made comparisons among different detection methods, including flame atomic absorption spectrometry (FAAS), graphite furnace atomic absorption specteometry (GFAAS), hydride generation atomic absorption specteometry (HGAAS), atomic fluorescence spectrometric (AFS), atomic emission spectrometry (AES), inductively coupled plasma-mass spectrum (ICP—MS), enzyme-linked immunosorbnent assay (ELISA), neutron activation analysis (NAA), stripping voltammetry (SV), enzyme inhibition method (EIM). Finally, the advantages and disadvantages of various detection methods were shown to provide insights into the application, research and development of the mineral elements determination in milk and dairy products.

Publication Date

6-28-2015

First Page

246

Last Page

250

DOI

10.13652/j.issn.1003-5788.2015.03.055

References

[1] Sola-Larraaga C,Navarro-Blasco I. Chemometric analysis of minerals and trace elements in raw cow milk from the community of Navarra, Spain[J]. Food Chemistry,2009,112(1):189~196.
[2] Pilarczyk R,Wójcik J,Czerniak P,et al. Concentrations of toxic heavy metals and trace elements in raw milk of Simmental and Holstein-Friesian cows from organic farm[J]. Environmental Monitoring and Assessment,2013,185(10):8 383~8 392.
[3] 张霞.天津检出13批次进口婴幼儿食品不合格[J].食品安全导刊,2014,2(8):65.
[4] 胡亦群, 宁慧青. 人体必需微量元素过量对健康的影响[J]. 太原科技,2008(5):22.
[5] 王绍林,刘荣辉,李文章,等. 矿泉微量元素对人体的生理作用[J]. 中国疗养医学,2003,12(3):161~163.
[6] Akinyele I O,Shokunbi O S. Comparative analysis of dry ashing and wet digestion methods for the determination of trace and heavy metals in food samples[J]. Food Chemistry,2015,173(6):682~684.
[7] Tuzen M,Silici S,Mendil D,et al. Trace element levels in honeys from different regions of Turkey[J]. Food Chemistry,2007,103(2):325~330.
[8] Rodríguez Rodríguez E M,Sanz Alaejos M,Díaz Romero C. Mineral concentrations in cow's milk from the Canary Island[J]. Journal of Food Composition and Analysis,2001,14(4):419~430.
[9] Kira C S,Maio F D,Maihara V A,et al. Comparison of partial digestion procedures for determination of Ca,Cr,Cu,Fe,K,Mg,Mn,Na,P and Zn in milk by inductively coupled plasma-optical emission spectrometry[J]. Journal of AOAC International,2004,87(1):151~156.
[10] Luo Yang,Zhang Bo,Chen Ming,et al. Rapid and simultaneous determination of essential minerals and trace elements in human milk by improved flame atomic absorption spectroscopy (FAAS) with microwave digestion[J]. Journal of Agricultural and Food Chemistry,2010,58(17):9 396~9 400.
[11] Santos D M,Pedroso M M,Costa L M,et al. A new procedure for bovine milk digestion in a focused microwave oven: gradual sample addition to pre-heated acid[J]. Talanta,2005,65(2):505~510.
[12] Andrade Korn M D G,da Boa Morte E S,Batista dos Santos D C M,et al. Sample preparation for the determination of metals in food samples using spectro analytical methods-a review[J]. Applied Spectroscopy Reviews,2008,43(2):67~92.
[13] Santos D C M B,Carvalho L S B,Lima D C,et al. Determination of micronutrient minerals in coconut milk by ICP OES after ultrasound-assisted extraction procedure[J]. Journal of Food Composition and Analysis,2014,34(1):75~80.
[14] Sola-Larraaga C,Navarro-Blasco I. Optimization of a slurry dispersion method for minerals and trace elements analysis in infant formulae by ICP OES and FAAS[J]. Food Chemistry,2009,115(3):1 048~1 055.
[15] 张金生,林静,李丽华,等.火焰原子吸收法测定蒙古奶茶中的钙,镁,锌[J].现代化工,2012,32(2):94~96.
[16] 乌尼尔,胡桂林,高娃,等.石墨炉原子吸收法测定乳和乳制品中的铬[J].中国乳品工业,2009(6):51~53.
[17] 陈少芳,谭国浩,陈秀芳.氢化物原子荧光法与石墨炉原子吸收法测定微量铅[J].中国卫生检验杂志,2009(5):1 049~1 050.
[18] Cava-Montesinos P,Cervera M L,Pastor A,et al. Hydride generation atomic fluorescence spectrometric determination of ultra traces of selenium and tellurium in cow milk[J]. Analytica Chimica Acta,2003,481(2):291~300.
[19] 吴雪莲,王文华.电感耦合等离子发射光谱法在食品分析中的应用[J].现代仪器,2009(6):47~49.
[20] Nascimento R S,Froes R E S,Silva N O C,et al. Quantification of inorganic constituents in Brazilian human milk by ICP OES[J]. Analytical Letters,2010,43(6):960~971.
[21] Tang Jun,Ying Ying,Pan Xiao-dong,et al. Elements analysis of infant milk formula by ICP-OES: a comparison of pretreatment methods[J]. Accreditation and Quality Assurance,2014,19(2):99~103.
[22] Khan N,Jeong I S,Hwang I M,et al. Analysis of minor and trace elements in milk and yogurts by inductively coupled plasma-mass spectrometry (ICP-MS)[J]. Food Chemistry,2014,147(3):220~224.
[23] Magbitang R A,Rodriguez I B. Cadmium and lead determination by ICPMS: Method optimization and application in carabao milk samples[J]. Science Diliman, 2012,24(1):156~158.
[24] Delehanty J B, Jones R M, Bishop T C, et al. Identification of important residues in metal-chelate recognition by monoclonal antibodies[J]. Biochemistry,2003,42(48):14 173~14 183.
[25] Xiang Jun-jian,Zhai Yi-fan,Tang Yong,et al. A competitive indirect enzyme-linked immunoassay for lead ion measurement using mAbs against the lead-DTPA complex[J]. Environmental Pollution,2010,158(5):1 376~1 380.
[26] Wasim M,Rehman S,Arif M,et al. Neutron activation analysis and atomic absorption spectrophotometry for the analysis of fresh, pasteurised and powder milk[J]. Radiochimica Acta International Journal for Chemical Aspects of Nuclear Science and Technology,2012,100(1):51~56.
[27] Gill K P,Zaidi J H,Ahmad S. Radiochemical neutron activation analysis for trace elements evaluation of human milk[J]. Radiochimica Acta/International Journal for Chemical Aspects of Nuclear Science and Technology,2003,91(9):547~552.
[28] 朱浩嘉,潘道东,顾愿愿,等.同位镀汞阳极溶出伏安法测定牛奶中镉,铅,铜[J].食品科学,2014,35(8):121~124.
[29] 刘京萍,李金,葛兴.葡萄糖氧化酶抑制法检测食品中镉, 锡, 铅的残留[J].北京农学院学报,2008,22(4):59~62.
[30] M Y Shukor,N A Baharom,N A Masdor. The development of an inhibitive determination method for zinc using a serine protease[J].Journal of Environmental Biology,2009,30(1):17~22.
[31] S Pirvutiou,I Surugiu. Flow injection analysis of mercury(II) based on enzyme inhibition and thermometric diction[J].Analyst,2001,126(3):1 612~1 616.
[32] 寇冬梅.快速检测重金属离子的酶膜生物传感器及其应用研究[D].重庆:西南大学,2008.
[33] Tadeusz K,Malgorzata M,Trojanowicz M. Inhibitive determination of mercury and other metal ions by potentiometric urea biosensor[J].Biosensors & Bioelectronics,2000,15(11):681~691.

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